Cats are not my favorite animal. HOWEVER, they translate REALLY WELL into comic form because they are easy to draw, easily recognizable, and very easy to emote with because their entire body is made of a liquid-rubber substance. With fur.
They are also very entertaining to watch and get to know… Cats can act as cool and calm as they want, but they are such slaves to instinct and they need people way more than they pretend to. Really, they’re a great analog for human life and relationships, which is perfect for a comic about my very human life portrayed by anthropomorphic animals.
Exaggerating expressions and reactions is helpful for cartoon art; it’s more believable than the very subtle expressions that real people generally use in normal situations. But since drawings are symbols, the opportunity to really sell the emotion is there. Cats alternate between the extremes naturally already, so why not?!
Plus fuzzy things are great.